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Syllabus for Chemistry in AIEEE

SECTION – A : PHYSICAL CHEMISTRY


UNIT 1 : 
Some Basic concepts in Chemistry : Matter and its nature, Dalton’s atomic theory; Concept of atom, molecule, element and compound; Physical quantities and their measurements in Chemistry, precision and accuracy, significant figures, S.I. Units, dimensional analysis; Laws of chemical combination; Atomic and molecular masses, mole concept, molar mass, percentage composition, empirical and molecular formulae; Chemical equations and stoichiometry.

UNIT 2 : 

States of Matter :

 Classification of matter into solid, liquid and gaseous states.

Gaseous State : Measurable properties of gases; Gas laws – Boyle’s law, Charle’s law, Graham’s law of diffusion, Avogadro’s law,Dalton’s law of partial pressure; Concept of Absolute scale of temperature; Ideal gas equation, Kinetic theory of gases (only postulates); Concept of average, root mean square and most probable velocities; Real gases, deviation from Ideal behaviour, compressibility factor, van der Waals equation, liquefaction of gases, critical constants.

Liquid State : Properties of liquids – vapour pressure, viscosity and surface tension and effect of temperature on them (qualitative treatment only).

Solid State : Classification of solids: molecular, ionic, covalent and metallic solids, amorphous and crystalline solids (elementary idea); Bragg’s Law and its applications; Unit cell and lattices, packing in solids (fcc, bcc and hcp lattices), voids, calculations involving unit cell parameters, imperfection in solids; Electrical, magnetic and dielectric properties.

UNIT 3 :

 Atomic Structure : 
Discovery of sub – atomic particles (electron, proton and neutron); Thomson and Rutherford atomic models and their limitations; Nature of electromagnetic radiation, photoelectric effect; Spectrum of hydrogen atom, Bohr model of hydrogen atom – its postulates, derivation of the relations for energy of the electron and radii of the different orbits, limitations of Bohr’s model; Dual nature of matter, de – Broglie’s relationship, Heisenberg uncertainty principle.

Elementary ideas of quantum mechanics, quantum mechanical model of atom, its important features, * and *2, concept of atomic orbitals as one electron wave functions; Variation of * and * 2 with r for 1s and 2s orbitals; various quantum numbers (principal, angular momentum and magnetic quantum numbers) and their significance; shapes of s, p and d – orbitals, electron spin and spin quantum number; Rules for filling electrons in orbitals – aufbau principle, Pauli’ s exclusion principle and Hund’s rule, electronic configuration of elements, extra stability of half – filled and completely filled orbitals.

UNIT 4 :

Chemical Bonding and Molecular Structure : Kossel – Lewis approach to chemical bond formation, concept of ionic and covalent bonds.

Ionic Bonding : Formation of ionic bonds, factors affecting the formation of ionic bonds; calculation of lattice enthalpy.

Covalent Bonding : Concept of electronegativity, Fajan’s rule, dipole moment; Valence Shell Electron Pair Repulsion (VSEPR) theory and shapes of simple molecules. Quantum mechanical approach to covalent bonding: Valence bond theory – Its important features, concept of hybridization involving s, p and d orbitals; Resonance.

Molecular Orbital Theory – Its important features, LCAOs, types of molecular orbitals (bonding, antibonding), sigma and pi – bonds, molecular orbital electronic configurations of homonuclear diatomic molecules, concept of bond order, bond length and bond energy.

Elementary idea of metallic bonding. Hydrogen bonding and its applications.

UNIT 5 :

CHEMICAL THERMODYNAMICS : Fundamentals of thermodynamics: System and surroundings, extensive and intensive properties, state functions, types of processes.

First law of thermodynamics – Concept of work, heat internal energy and enthalpy, heat capacity, molar heat capacity; Hess’s law of constant heat summation; Enthalpies of bond dissociation, combustion, formation, atomization, sublimation, phase transition, hydration, ionization and solution.

Second law of thermodynamics – Spontaneity of processes; DS of the universe and DG of the system as criteria for spontaneity, DGo (Standard Gibbs energy change) and equilibrium constant.

UNIT 6 : 

SOLUTIONS : Different methods for expressing concentration of solution – molality, molarity, mole fraction, percentage (by volume and mass both), vapour pressure of solutions and Raoult’s Law – Ideal and non – ideal solutions, vapour pressure – composition, plots for ideal and non – ideal solutions; Colligative properties of dilute solutions – relative lowering of vapour pressure, depression of freezing point, elevation of boiling point and osmotic pressure; Determination of molecular mass using colligative properties; Abnormal value of molar mass, van’t Hoff factor and its significance.

UNIT 7 : 

EQUILIBRIUM : Meaning of equilibrium, concept of dynamic equilibrium. Equilibria involving physical processes: Solid – liquid, liquid – gas and solid – gas equilibria, Henry’s law, general characterics of equilibrium involving physical processes.

Equilibria involving Chemical Processes : Law of chemical equilibrium, equilibrium constants (Kp and Kc) and their significance, significance of DG and DGo in chemical equilibria, factors affecting equilibrium concentration, pressure, temperature, effect of catalyst; Le Chatelier’s principle.

Ionic equilibrium : Weak and strong electrolytes, ionization of electrolytes, various concepts of acids and bases (Arrhenius, Br’nsted – Lowry and Lewis) and their ionization, acid – base equilibria (including multistage ionization) and ionization constants, ionization of water, pH scale, common ion effect, hydrolysis of salts and pH of their solutions, solubility of sparingly soluble salts and solubility products, buffer solutions.

UNIT 8 :

 REDOX REACTIONS AND ELECTROCHEMISTRY : Electronic concepts of oxidation and reduction, redox reactions, oxidation number, rules for assigning oxidation number, balancing of redox reactions. Eectrolytic and metallic conduction, conductance in electrolytic solutions, specific and molar conductivities and their variation with concentration: Kohlrausch’s law and its applications.

Electrochemical Cells – Electrolytic and Galvanic cells, different types of electrodes, electrode potentials including standard electrode potential, half – cell and cell reactions, emf of a Galvanic cell and its measurement; Nernst equation and its applications; Relationship between cell potential and Gibbs’ energy change; Dry cell and lead accumulator; Fuel cells; Corrosion and its prevention.

UNIT 9 :

CHEMICAL KINETICS : Rate of a chemical reaction, factors affecting the rate of reactions : concentration, temperature, pressure and catalyst; elementary and complex reactions, order and molecularity of reactions, rate law, rate constant and its units, differential and integral forms of zero and first order reactions, their characteristics and half – lives, effect of temperature on rate of reactions – Arrhenius theory, activation energy and its calculation, collision theory of bimolecular gaseous reactions (no derivation).

UNIT 10 : 

SURFACE CHEMISTRY : Adsorption- Physisorption and chemisorption and their characteristics, factors affecting adsorption of gases on solids – Freundlich and Langmuir adsorption isotherms, adsorption from solutions. Catalysis – Homogeneous and heterogeneous, activity and selectivity of solid catalysts, enzyme catalysis and its mechanism.

Colloidal state – distinction among true solutions, colloids and suspensions, classification of colloids – Iyophilic, lyophobic; multi molecular, macromolecular and associated colloids (micelles), preparation and properties of colloids – Tyndall effect, Brownian movement, electrophoresis, dialysis, coagulation and flocculation; Emulsions and their characteristics.

SECTION – B - INORGANIC CHEMISTRY

UNIT 11 :

 CLASSIFICATION OF ELEMENTS AND PERIODICITY IN PROPERTIES : Modem periodic law and present form of the periodic table, s, p, d and f block elements, periodic trends in properties of elements­atomic and ionic radii, ionization enthalpy, electron gain enthalpy, valence, oxidation states and chemical reactivity.

UNIT 12 : 

GENERAL PRINCIPLES AND PROCESSES OF ISOLATION OF METALS : Modes of occurrence of elements in nature, minerals, ores; steps involved in the extraction of metals – concentration, reduction (chemical and electrolytic methods) and refining with special reference to the extraction of Al, Cu, Zn and Fe; Thermodynamic and electrochemical principles involved in the extraction of metals.

UNIT 13 :

 HYDROGEN : Position of hydrogen in periodic table, isotopes, preparation, properties and uses of hydrogen; Physical and chemical properties of water and heavy water; Structure, preparation, reactions and uses of hydrogen peroxide; Classification of hydrides – ionic, covalent and interstitial; Hydrogen as a fuel.

UNIT 14 : 

S – BLOCK ELEMENTS (ALKALI AND ALKALINE EARTH METALS) : Group – 1 and 2 Elements General introduction, electronic configuration and general trends in physical and chemical properties of elements, anomalous properties of the first element of each group, diagonal relationships.

Syllabus for Physics in AIEEE

Unit 1: Units And Measurement
Units for measurement, system of units ;S.I., fundamental and derived units. Dimensions and their applications.

Unit 2: Description Of Motion In One Dimension
Motion in a straight line, uniform and non-uniform motion, their graphical representation. Uniformly accelerated motion, and its applications

Unit 3: Description Of Motion In Two And Three Dimensions
Scalars and vectors, vector addition, a real number, zero vector and its properties. Resolution of vectors. Scalar and vector products, uniform circular motion and its applications projectile motion.


Unit 4: Laws Of Motion
Force and inertia ; Newton's Laws of Motion. Conservation of linear momentum and its applications, rocket propulsion, friction ; laws of friction

Unit 5 Work, Energy And Power
Concept of work, energy and power. Energy � kinetic and potential. Conservation of energy and its applications, Elastic collisions in one and two dimensions. Different forms of energy.

Unit 6: Rotational Motion And Moment Of Inertia
Centre of mass of a two-particle system. Centre of mass of a rigid body, general motion of a rigid body, nature of rotational motion, torque, angular momentum, its conservation and applications. Moment of Inertia, parallel and perpendicular axes theorem, expression of moment of inertia for ring, disc and sphere.

Unit 7: Gravitation
Acceleration due to gravity, one and two-dimensional motion under gravity. Universal law of gravitation, variation in the acceleration due to gravity of the earth. Planetary motion, Kepler's laws, artificial satellite ;geostationary satellite, gravitational potential energy near the surface of earth, gravitational potential and escape velocity.

Unit 8: Solids And Fluids
Inter-atomic and Inter-molecular forces, states of matter.

• Solids : Elastic properties, Hook's law, Young's modulus, bulk modulus, modulus of rigidity.
• Liquids : Cohesion and adhesion. Surface energy and surface tension. Flow of fluids, Bernoulli's theorem and its applications. Viscosity, Stoke's Law, terminal velocity.

Unit 9: Oscillations
Periodic motion, simple harmonic motion and its equation of motion, energy in S.H.M., Oscillations of a spring and simple pendulum.

Unit 10: Waves
Wave motion, speed of a wave, longitudinal and transverse waves, superposition of waves, progressive and standing waves, free and forced Oscillations, resonance, vibration of strings and air-columns, beats, Doppler effect.

Unit 11: Heat And Thermodynamics
Thermal expansion of solids, liquids and gases and their specific heats, Relationship between Cp and Cv for gases, first law of thermodynamics, thermodynamic processes. Second law of thermodynamics, Carnot cycle, efficiency of heat engines.

Unit 12: Transference Of Heat
Modes of transference of heat. Thermal conductivity. Black body radiations, Kirchoff's Law, Wien's law, Stefan's law of radiation and Newton 's law of cooling.

Unit 13: Electrostatics
Electric charge ,its unit and conservation, Coulomb's law, dielectric constant, electric field, lines of force, field due to dipole and its behaviour in a uniform electric field, electric flux, Gauss's theorem and its applications. Electric potential, potential due to a point charge. Conductors and insulators, distribution of charge on conductors. Capacitance, parallel plate capacitor, combination of capacitors, energy of capacitor.

Unit 14: Current Electricity
Electric current and its unit, sources of energy, cells- primary and secondary, grouping of cells resistance of different materials, temperature dependence, specific resistivity, Ohm's law, Kirchoff's law, series and parallel circuits. Wheatstone Bridge with their applications and potentiometer with their applications.

Unit 15: Thermal And Chemical Effects Of Currents
Heating effects of current, electric power, simple concept of thermo-electricity ; Seeback effect and thermocouple, Chemical effect of current ; Faraday's laws of electrolysis.

Unit 16: Magnetic Effects Of Currents
Oersted's experiment, Bio-Savert's law, magnetic field due to straight wire, circular loop and solenoid, force on a moving charge in a uniform magnetic field (Lorentz force), forces and torques on currents in a magnetic field, force between two current carrying wires, moving coil galvanometer and conversion to ammeter and voltmeter.

Unit 17: Magnetostatics
Bar magnet, magnetic field, lines of force, torque on a bar magnet in a magnetic field, earth's magnetic field, para, dia and ferro magnetism, magnetic induction, magnetic susceptibility.

Unit 18: Electromagnetic Induction And Alternating Currents
Induced e.m.f., Faraday's Law, Lenz's Law, Self and Mutual Inductance, alternating currents, impedance and reactance, power In a.c.Circuits with L.C. And R Series Combination, resonant circuits. Transformer and A.C. generator.

Unit 19: Ray Optics
Reflection and refraction of light at plane and curved surfaces, total internal reflection, optical fibre; deviation and dispersion of light by a prism; Lens formula, magnification and resolving power; microscope and telescope.

Unit 20: Wave Optics
Wave nature of light; Interference ,Young's double slit experiment. Diffraction - diffraction due to a single slit. Elementary idea of polarization.

Unit 21: Electromagnetic Waves
Electromagnetic waves and their characteristics, Electromagnetic wave spectrum from gamma to radio waves ; propagation of EM waves in atmosphere.

Unit 22: Electron And Photons
Charge on an electron, e/m for an electron, photoelectric effect and Einstein's equation of photoelectric effect.

Unit 23: Atoms, Molecules And Nuclei
Alpha - particles scattering experiment, Atomic masses, size of the nucleus; radioactivity; Alpha, beta and gamma particles/ rays and their properties, radioactive decay law, half life and mean life of radio-active nuclei, binding energy, mass energy relationship, nuclear fission and nuclear fusion.

Unit 24: Solids And Semi-Conductors Devices
Energy bands in solids, conductors, insulators and semi-conductors, pn junction, diodes, diode as rectifier, transistor action, transistor as an amplifier.

Mathematics syllabus for AIEEE

UNIT 1:	SETS, RELATIONS AND FUNCTIONS:
	Sets and their representation; Union, intersection and complement of sets and their algebraic properties; Power set; Relation, Types of relations, equivalence relations, functions;. one-one, into and onto functions, composition of functions.
UNIT 2:	COMPLEX NUMBERS AND QUADRATIC EQUATIONS:
	Complex numbers as ordered pairs of reals, Representation of complex numbers in the form a+ib and their representation in a plane, Argand diagram, algebra of complex numbers, modulus and argument (or amplitude) of a complex number, square root of a complex number, triangle inequality, Quadratic equations in real and complex number system and their solutions. Relation between roots and co-efficients, nature of roots, formation of quadratic equations with given roots.
UNIT 3:	MATRICES AND DETERMINANTS:
	Matrices, algebra of matrices, types of matrices, determinants and matrices of order two and three. Properties of determinants, evaluation of determinants, area of triangles using determinants. Adjoint and evaluation of inverse of a square matrix using determinants and elementary transformations, Test of consistency and solution of simultaneous linear equations in two or three variables using determinants and matrices.
UNIT 4:	PERMUTATIONS AND COMBINATIONS:
	Fundamental principle of counting, permutation as an arrangement and combination as selection, Meaning of P (n,r) and C (n,r), simple applications.
UNIT 5:	MATHEMATICAL INDUCTION:
	Principle of Mathematical Induction and its simple applications.
UNIT 6:	BINOMIAL THEOREM AND ITS SIMPLE APPLICATIONS:
	Binomial theorem for a positive integral index, general term and middle term, properties of Binomial coefficients and simple applications.
UNIT 7:	SEQUENCES AND SERIES:
	Arithmetic and Geometric progressions, insertion of arithmetic, geometric means between two given numbers. Relation between A.M. and G.M. Sum upto n terms of special series: Sn, Sn2, Sn3. Arithmetico - Geometric progression.
UNIT 8:	LIMIT, CONTINUITY AND DIFFERENTIABILITY:
	Real - valued functions, algebra of functions, polynomials, rational, trigonometric, logarithmic and exponential functions, inverse functions. Graphs of simple functions. Limits, continuity and differentiability. Differentiation of the sum, difference, product and quotient of two functions. Differentiation of trigonometric, inverse trigonometric, logarithmic, exponential, composite and implicit functions; derivatives of order upto two. Rolle’s and Lagrange’s Mean Value Theorems. Applications of derivatives: Rate of change of quantities, monotonic - increasing and decreasing functions, Maxima and minima of functions of one variable, tangents and normals.
UNIT 9:	INTEGRAL CALCULUS:
	Integral as an anti - derivative. Fundamental integrals involving algebraic, trigonometric, exponential and logarithmic functions. Integration by substitution, by parts and by partial fractions. Integration using trigonometric identities. Evaluation of simple integrals of the type Integral as limit of a sum. Fundamental Theorem of Calculus. Properties of definite integrals. Evaluation of definite integrals, determining areas of the regions bounded by simple curves in standard form.
UNIT 10:	DIFFERENTIAL EQUATIONS:
	Ordinary differential equations, their order and degree. Formation of differential equations. Solution of differential equations by the method of separation of variables, solution of homogeneous and linear differential equations of the type: dy -- + p (x) y = q (x) dx
UNIT 11:	CO-ORDINATE GEOMETRY:
	Cartesian system of rectangular co-ordinates in a plane, distance formula, section formula, locus and its equation, translation of axes, slope of a line, parallel and perpendicular lines, intercepts of a line on the coordinate axes. Straight lines Various forms of equations of a line, intersection of lines, angles between two lines, conditions for concurrence of three lines, distance of a point from a line, equations of internal and external bisectors of angles between two lines, coordinates of centroid, orthocentre and circumcentre of a triangle, equation of family of lines passing through the point of intersection of two lines. Circles, conic sections Standard form of equation of a circle, general form of the equation of a circle, its radius and centre, equation of a circle when the end points of a diameter are given, points of intersection of a line and a circle with the centre at the origin and condition for a line to be tangent to a circle, equation of the tangent. Sections of cones, equations of conic sections (parabola, ellipse and hyperbola) in standard forms, condition for y = mx + c to be a tangent and point (s) of tangency.
UNIT 12:	THREE DIMENSIONAL GEOMETRY:
	Coordinates of a point in space, distance between two points, section formula, direction ratios and direction cosines, angle between two intersecting lines. Skew lines, the shortest distance between them and its equation. Equations of a line and a plane in different forms, intersection of a line and a plane, coplanar lines.
UNIT 13:	VECTOR ALGEBRA:
	Vectors and scalars, addition of vectors, components of a vector in two dimensions and three dimensional space, scalar and vector products, scalar and vector triple product.
UNIT 14:	STATISTICS AND PROBABILITY:
	Measures of Dispersion: Calculation of mean, median, mode of grouped and ungrouped data. Calculation of standard deviation, variance and mean deviation for grouped and ungrouped data. Probability: Probability of an event, addition and multiplication theorems of probability, Baye’s theorem, probability distribution of a random variate, Bernoulli trials and Binomial distribution.
UNIT 15:	TRIGONOMETRY:
	Trigonometrical identities and equations. Trigonometrical functions. Inverse trigonometrical functions and their properties. Heights and Distances.
UNIT 16:	MATHEMATICAL REASONING:
	Statements, logical operations and, or, implies, implied by, if and only if. Understanding of tautology, contradiction, converse and contrapositive